Lead in Washington D.C.'s Water Supply
The February 29th, 2004 Sunday edition of the Washington Post carried
as its lead story the discovery of high lead levels in Washington's drinking
water. The chemistry involved is directly related to topics just
covered and that will be covered. Answer the below questions using
SciFinder and other resources. Here is a link
to the Washington Post URL concerning this issue:
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Write the reaction that occurs in order for lead from solid pipes to become
soluble in water. Classify the type of reaction this is.
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Orthophosphates are known as corrosion inhibitors have been identified
as a solution to this problem. Identify specifically what is meant
by orthophosphates. Write the chemical reaction that occurs during
corrosion inhibition.
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It has been stated that when the water becomes more corrosive (i.e. the
pH becomes more acidic), the corrosion inhibition reaction does not work
as well. Write the applicable set of equations that shows this and
explain how lowering the pH will cause equilibria shifts.
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Explain why lime is used to adjust pH to make water less corrosive; support
your answers with a set of applicable chemical equations.
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What is the federal drinking water limit for lead in units of mg lead per
liter of water (remember that a liter of water has a mass of approximately
1 kg)? What levels of lead have been found in Washington's water
supply?
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What are the toxic effects of lead? Find three scientific abstracts
using SciFinder that discuss these and write a paragraph in your own words
that summarizes the significance of each of these.
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What immediate measures are being taken to remove lead from the affected
household's water supply? Explain the basis for how they work chemically.